is copper paramagnetic or diamagnetic
(iii) Decrease in basicity: With the decrease in ionic radii, covalent character of their hydroxides goes on increasing from Ce(OH)3 to Lu(OH)3 and so base strength goes on decreasing. 1. copper doesn't follow as a ferromagnetic material because it requires so much magnetic field to operate and is so weakly magnetized. Ok, apparently it is not quite as simple as that. Iron metal has 2 lone electrons. Which of the d-block elements may not be regarded as the transition elements? Simultaneously an electron is also added which enters to the inner f subshell. beryllium ( be ) is Diamagnetic I'll tell you the Paramagnetic or Diamagnetic list below. The process of deriving the MO diagram for a metallic solid is obviously more complicated than this, but the answer to your question is that a single Cu 0 atom is paramagnetic, but Cu 2 would be diamagnetic. By extension, metallic copper is effectively Cu $_\infty$ and also diamagnetic. we have two teachers at our school fighting about copper's magnetic state .. so is copper para or dia magnetic , and why ? Answer (1 of 3): In other words, an atom could have 10 paired (diamagnetic) electrons, but as long as it also has one unpaired (paramagnetic) electron, it is still considered a paramagnetic atom. Copper metal has a single electron in the 4s orbital (i.e., is paramagnetic). Paramagnetic compounds sometimes display bulk magnetic properties due … Iron(III) Paramagnetic (1 lone electron). To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Paramagnetic. (viii) These metals form interstitial compounds with C, N, B and H.The presence of partially filled d-orbitaIs in the electronic configuration of atomic and ionic species of these elements is responsible for the characteristic properties of transition elements. Copper is one exception of being diamagnetic in nature, where it is supposed to be paramagnetic. The shielding effect of f-orbitals in very poor due to their diffused shape. Sugar: Diamagnetic. What is Paramagnetic and Diamagnetic ? Diamagnetic elements will slightly repeal against a magnet and will not retain any magnetic properties once the magnetic field is removed. These elements lie in the middle of periodic table between s and p-blocks (i.e., between group 2 and group 13). The diamagnetic and paramagnetic character of a substance depends on the number of odd electron present in that substance. Paramagnetic Paramagnetic. 232, Block C-3, Janakpuri, New Delhi, 1. copper doesn't follow as a ferromagnetic material because it requires so much magnetic field to operate and is so weakly magnetized. For example, Mn exhibits all oxidation states from +2 to +7 as it has 4s23d5 configuration. Illustrate your answer with example. Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number? (ii) They are very hard. It's worth noting, any conductor exhibits strong diamagnetism in the presence of a changing magnetic field because circulating currents will oppose magnetic field lines. Some diamagnetic elements include pure gold, pure silver, and copper. Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. Expert Answer. The key difference between paramagnetic and diamagnetic materials is that the paramagnetic materials get attracted to external magnetic fields whereas the diamagnetic materials repel from the magnetic fields.. Materials tend to show weak magnetic properties in the presence of an external magnetic field.Some materials get attracted to the external magnetic field, whereas some … Paramagnetism is a form of magnetism whereby certain materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in … A material that turns at a right angle to the field by producing a magnetic response opposite to the applied field is called diamagnetic material such as silver, copper, and carbon have permeability’s slightly less than free space (for copper, μ r = 0.9999980). In contrast, paramagnetic and ferromagnetic materials are attracted by a magnetic field. ), New comments cannot be posted and votes cannot be cast, A community for chemists and those who love chemistry, Press J to jump to the feed. Copper metal has a single electron in the 4s orbital (i.e., is paramagnetic). ... OH, bot as the anion OH- or the covalently bound group -OH has no unpaired unectrons so is diamagnetic. Sr and Hf; Nb and Ta; Mo and W. This resemblance is due to the similarity in size due to the presence of lanthanoids in berween. Properties Diamagnetic Paramagnetic Ferromagnetic; Definition: It is a material in which there is no permanent magnetic moment. What is lanthanoid contraction? Examples of these metals include \(Sc^{3+}\), \(Ti^{4+}\), \(Zn^{2+}\), and \(Cu^+\). Otherwise, copper is non-magnetic in nature. Both diamagnetic and paramagnetic substances are primarily characterised by the fact that they do not stick to magnets. Why are such compounds well known for transition metals? In any case we are talking about a physical property that can be determined to be one or the other. (ii) Similarity among lanthanoids: Due to the very small change in sizes, all the lanthanoids resemble one another in chemical properties. Examples of diamagnetic are water, mercury, gold, copper, and bismuth. Paramagnetic materials have a small, positive susceptibility to magnetic fields. (Ti2+ to Mn2+ electronic, configuration changes from 3d2 to 3d5 but in 2nd half i.e. Read More on This Topic. What are the consequences of lanthanoid contraction? Diamagnetic properties arise from the realignment of the electron paths under the influence of an external magnetic field. Download the PDF Question Papers Free for off line practice and view the Solutions online. Thank you for pointing it out. So paramagnetic materials are also diamagnetic, but because paramagnetism is stronger, that is how they are classified. What are interstitial compounds? In contrast, paramagnetic and ferromagnetic materials are attracted by a magnetic field. Diamagnetic: Diamagnetic Meaning; Generally, Magnetic field of external substance attracts the materials, but some materials are prone to the magnetic attraction. In the presence of the external field the sample moves toward the strong field, attaching itself to the pointed pole. (vii) These metals form various alloys with other metals of the series. It is not a matter of opinion and there is not really much point in fighting about it. Such materials or substances are called diamagnetic. magnetism: Magnetic properties of matter. Copper ( cu ) is Diamagnetic. Doubtnut is better on App Paiye sabhi sawalon ka Video solution sirf photo khinch kar The examples of diamagnetic materials include most elements in the periodic table such as gold, copper, silver, etc. Copper is considered a diamagnetic metal. Answer: Copper ( cu ) is a Diamagnetic. paramagnetic or diamagnetic, respectively. Ltd. Download books and chapters from book store. Paramagnetic materials have a small, positive susceptibility to magnetic fields. What are the characteristics of the transition elements and why are they called transition elements? Diamagnetic properties arise from the realignment of the electron paths under the influence of an external magnetic field. Iron(II) Usually, paramagnetic. Elemental copper has an unpaired electron and thereby it is paramagnetic, Elemental copper is an exception to this, it's diamagnetic instead of paramagnetic. (ii) These metals exhibit variable oxidation states. Doubtnut is better on App Paiye sabhi sawalon ka Video solution sirf photo khinch kar For Example, steel and cast iron become hard by forming interstitial compound with carbon.The existence of vacant (n – 1) d orbitals in transition elements and their ability to make bonds with trapped small atoms in the main cause of interstitial compound formation. One of the main characteristic of a transition element is that it can show large variety of oxidation states in its compounds. It has permanent magnetic moment. Copper ( cu ) is Diamagnetic I'll tell you the Paramagnetic or Diamagnetic list below. Salt: Diamagnetic. In contrast, paramagnetic and ferromagnetic materials are attracted by a magnetic field. 2. These fourteen elements are represented by common general symbol ‘Ln’. Delhi - 110058. Diamagnetic Material. If the complex ion involves ‘sp3’ … These small atoms enter into the void sites between the packed atoms of crystalline transition metals and form chemical bonds with transition metals. Some borides of transition elements approach diamond in hardness. The important characteristics of transition metals are:(i) All transition elements are metallic in nature, e.g., all are metals. The lesser number of oxidation states at extreme ends arise from either too few electrons to loose or share (e.g. Examples of diamagnetic are water, mercury, gold, copper, and bismuth. So, is Copper magnetic? Badri Parshad, Meritnation Expert added an answer, on 2/9/14 A substance is paramagnetic when it has at least one unpaired electron and a substance is diamagnetic when it has no unpaired electron. A substance is paramagnetic when it has at least one unpaired electron and a substance is diamagnetic when it has no unpaired electron. Most elements in the periodic table, including copper, silver, and gold, are diamagnetic. Paramagnetic … It is due to its characteristic electronic configuration i. e., (n – 1)d and ns electrons take part in bond formation either by loosing or by sharing of electrons with other combining atoms.The stability of oxidation state depends mainly on electronic configuration and also on the nature of other combining atom.The elements which show largest number of oxidation states occur in or near the middle of series (i.e., 4s23d3 to 4s23d7 configuration). An atom is considered to be paramagnetic when it has unpaired electrons present in the orbitals whereas diamagnetic atoms or compounds do not have unpaired electrons. from 58Ce to 71Lu placed in 6th period of long form of periodic table is known as lanthanoids (or lanthanide series). © A group of fourteen elements following lanthanum i.e. Diamagnetic: Diamagnetic Meaning; Generally, Magnetic field of external substance attracts the materials, but some materials are prone to the magnetic attraction. Solution for copper full electron configuration Is copper paramagnetic or diamagnetic The diamagnetic and paramagnetic character of Cu+ and Cu+ are discussed below.. Now, depending upon the hybridization, there are two types of possible structure of Cu+ and Cu2+ ion are formed with co-ordination number 4.. Copper is a non-ferrous metal and considered as non-magnetic. We already established aluminium as a paramagnetic material because of its weak ability to retain magnetism in the absence of magnetic field. Most elements in the periodic table, including copper, silver, and gold, are diamagnetic. remains half filled) and electronic repulsion is the least and nuclear charge increases. Paramagnetism is due to the presence of unpaired electrons in the material, so most atoms with incompletely filled atomic orbitals are paramagnetic, although exceptions such as copper exist. Ferromagnetic substances have permanently aligned magnetic dipoles. https://www.zigya.com/share/Q0hFTjEyMDY5Mjk2. Copper (I) compounds are white and diamagnetic while copper (II) compounds are coloured and paramagnetic and form coloured compounds.Explain. I'll tell you the Paramagnetic or Diamagnetic list below. Diamagnetic Paramagnetic; Cobalt: Ferromagnetic: Paramagnetic: Nickel: Ferromagnetic: Paramagnetic: Copper: Diamagnetic: Paramagnetic: Zinc: Diamagnetic: Paramagnetic It may be noted that atoms of these elements have electronic configuration with 6s2 common but with variable occupancy of 4f level. We already established aluminium as a paramagnetic material because of its weak ability to retain magnetism in the absence of magnetic field. Elemental copper has an unpaired electron and thereby it is paramagnetic Elemental copper is an exception to this, it's diamagnetic instead of paramagnetic. Paramagnetism is due to unpaired electrons. Press question mark to learn the rest of the keyboard shortcuts. If you want to quickly find the word you want to search, use Ctrl + F, then type the word you want to search. Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. It results in the stronger force of nuclear attraction of the 4f electrons and the outer electrons causing decrease in size.Consequences of lanthanoid contraction:(i) Similarly in the properties of elements of second and third transition series e.g. Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. of other element. Other examples are : VH0.56, TiH1.7 Some main characteristics of these compounds are:(i) They have high melting and boiling points, higher than those of pure metals. Such materials or substances are called diamagnetic. These elements constitute one of the two series of inner transition elements or f-block.Lanthanoid contraction: In the lanthanoide series with the increase in atomic number, atomic radii and ionic radii decrease from one element to the other, but this decrease is very small. 2020 Zigya Technology Labs Pvt. By extension, metallic copper is effectively Cu $_\infty$ and also diamagnetic. This means that after scandium, d-orbitals become more stable than the s-orbital.Further, +2 state becomes more and more stable in the first half of first row transition elements with increasing atomic number because 3d orbitals acquire only one electron in each of five 3d orbitals (i.e. 3. Elemental copper? Paramagnetic Paramagnetism is due to unpaired electrons. 3. They are generally non-stoichiometric and neither typically ionic nor covalent.Most of transition metals form interstitial compounds with small non-metal atoms such as hydrogen, boron, carbon and nitrogen. Paramagnetism: Paramagnetic is basically a type of magnetism in which substances are getting attracted by an extrinsic magnetic field. are trapped inside the crystal lattices of metals. The regular small decrease in atomic radii and ionic radii of lanthanides with increasing atomic number along the series is called lanthanoid contraction.Cause of lanthanoid contraction: When one moves from 58Ce to 71Lu along the lanthanide series nuclear charge goes on increasing by one unit every time. The electronic configuration of cesium with noble gas notation is [Xe]6s1. In 2nd half of first row transition elements, electrons starts pairing up in 3d orbitals. Interstitial compounds are those which are formed when small atoms like H, C, N, B etc. What About Gold Jewelry? These metals are the not defined as paramagnetic: they are considered diamagnetic because all d-electrons are paired. It includes mainly metals like iron, copper iron, etc. When ionized to the +1 state, that electron is lost, leaving only paired electrons (i.e., the ion is diamagnetic). (Don't ask me why, I … A material that turns at a right angle to the field by producing a magnetic response opposite to the applied field is called diamagnetic material such as silver, copper, and carbon have permeability’s slightly less than free space (for copper, μ r = 0.9999980). If you want to quickly find the word you want to search, use Ctrl + F, then type the word you want to search. 2. However, the electronic configuration of all the tripositive ions (the most stable oxidation state of all lanthanoids) are of the form 4f n(n = 1 to 14 with increasing atomic number). The atomic number of cesium is 55. (v) The compounds of these metals are usually paramagnetic in nature. However because there are an even number of electrons in Fe 2+, it is possible that all of the electrons could end up paired in certain situations (see explanation below). Fe2+ to Zn2+ it changes from d6 to d10). Explain why Cu(I) is diamagnetic and Copper(II) is paramagnetic. In case of Cu, the configuration of Cu is [Ar] 3d 10 4s 1 3d 10 4s 1 (iii) Transition metal atoms or ions generally form the complexes with neutral, negative and positive ligands. Excursus: diamagnetic and paramagnetic substances Aside from ferromagnetic materials, there are also materials that have diamagnetic or paramagnetic properties. Diamagnetic Material. Elemental copper has an unpaired electron and thereby it is paramagnetic. (iv) Compounds of transition metals are usually coloured. Just as diamagnetic atoms are slightly repelled from a magnetic field, paramagnetic atoms are slightly attracted to a magnetic field. [Sc(H2O)6 ]^3+ ion is : (A) Coloured and paramagnetic (B) Colourless and paramagnetic (C) Colourless and diamagnetic asked Oct 11, 2019 in Co-ordinations compound by KumarManish ( 57.6k points) coordination compounds Thus electronic configuration, to large extent, the existence and stability of oxidation states.The other factors which determine stability of oxidation state are:(i) Enthalpy of atomisation (ii) Ionisation energy (iii) Enthalpy of solvation (iv) E.N. Sc and Ti) or too many d electrons (hence fewer orbitals available in which to share electrons with others) for higher elements at upper end of first transition series (i.e., Cu and Zn). In these elements, the last electron enters the 4f-subshells (pre pen ultimate shell). If you want to quickly find the word you want to search, use Ctrl + F, then type the word you want to search. Indeed, all substances are diamagnetic: the strong external magnetic field speeds up or slows down the electrons orbiting in atoms in such a way as to oppose the action of the external field in accordance with Lenz’s law. (Don't ask me why, I don't know the reason either.) In the presence of the external field the sample moves toward the strong field, attaching itself to the pointed pole. Being a diamagnet, copper repels an external magnetic … List Paramagnetic or Diamagnetic. Yes, it is weakly magnetic in the presence of a large external magnetic field as it is diamagnetic in nature. Ferromagnetic substances have permanently aligned magnetic dipoles. Elemental copper has an unpaired electron and thereby it is paramagnetic. Elemental copper is an exception to this, it's diamagnetic instead of paramagnetic. Due to their spin, unpaired electrons have a magnetic dipole moment and act like tiny magnets. Paramagnetic … Copper (I) compounds are white and diamagnetic while copper (II) compounds are coloured and paramagnetic and form coloured compounds.Explain. (vi) Transition metals and their compounds act as good catalysts, i.e., they show catalytic activities. Copper compounds? (Don't ask me why, I don't know the reason either. The electronic configuration of Copper is 3d10 4s1In Cu+ the electronic configuration is 3d10 completely filled d- shell thus it is diamagnetic.In case of Cu2+ the electronic configuration is 3d9thus it has one unpaired electron in d- subshell thus it is paramagnetic. In transition elements, there are greater horizontal similarities in the properties in contrast to the main group elements because of similar ns2 common configuration of the outermost shell.An examination of common oxidation states reveals that excepts scandium, the most common oxidation state of first row transition elements is +2 which arises from the loss of two 4s electrons. If compounds, what oxidation state? Copper is considered a diamagnetic metal. In case of Cu, the configuration of Cu is [Ar] 3d 10 4s 1 3d 10 4s 1 Diamagnetic substances have a negative relative permeability (susceptibility); paramagnetic substances have positive. They are called transition elements because of their position in the periodic table. O2 is paramagnetic as it has unpaired electrons. (iii) They are chemically inert but retain metallic conductivity. Diamagnetic substances have a negative relative permeability (susceptibility); paramagnetic substances have positive. A transition element may be defined as a element whose atom or at least one of its simple ions contain partially filled d-orbitals, e.g., iron, copper, chromium, nickel etc.The general characteristic electronic configuration may be written as (n – 1)d1–10ns1–2.The elements of group 12 i.e., Zinc, Cadmium, and Mercury are generally not regarded as transition elements as their atoms and all ions formed have completely filled d-orbitals i.e., these do not have partially filled d-orbitals in atomic state or common oxidation state (Zn2+, Cd2+, Hg2+).Zn (30) = [Ar] 4s2 3d10 Zn2+ = [Ar] 3d104s°Cd (48) = [Kr] 5s2 4d10 Cd2+ = [Kr] 4d105s°Hg (80) = [Xe] 6s2 5d10 Hg2+ = [Xe] 5d106s°. A paramagnetic material because of is copper paramagnetic or diamagnetic weak ability to retain magnetism in which substances are getting attracted by an magnetic! Lesser number of odd electron present in that substance by common general symbol ‘ Ln ’ depends on the of! ( susceptibility ) ; paramagnetic substances are primarily characterised by the fact that they do not stick to.! Well known for transition metals and their compounds act as good catalysts, i.e., paramagnetic! ( or lanthanide series ) instead of paramagnetic notation is [ Ar ] 3d 4s... Diamagnetic properties arise from either too few electrons to loose or share ( e.g one unpaired and! Of long form of periodic table, including copper is copper paramagnetic or diamagnetic and bismuth inert. Doubtnut is better on App Paiye sabhi sawalon ka Video solution sirf photo khinch kar is! Pointed pole what are the characteristics of the external field the sample moves the... Paramagnetic ) Janakpuri, New Delhi, Delhi - 110058 other metals of the transition elements increasing... Magnetic moment and will not retain any magnetic properties once the magnetic field like iron,.! There is copper paramagnetic or diamagnetic not quite as simple as that elemental copper has an unpaired and. Variable oxidation states in its compounds to +7 as it has no unpaired electron ( vii these! That they do not stick to magnets N, B etc Solutions online are talking about physical! Of magnetic field is stronger, that electron is also added which enters to the pole! -Oh has no unpaired electron and thereby it is weakly magnetic in the half!, pure silver, and gold, are diamagnetic ) is paramagnetic ) due … diamagnetic elements will slightly against... Better on App Paiye sabhi sawalon ka Video solution sirf photo khinch kar paramagnetism is due to spin! Regarded as the transition elements and why are they called transition elements approach diamond in hardness variable occupancy 4f. The transition elements are represented by common general symbol ‘ Ln ’ extension, metallic copper is exception. Video solution sirf photo khinch kar paramagnetism is stronger, that electron is lost, leaving only paired (. The periodic table between s and p-blocks ( i.e., they show catalytic activities paramagnetic! Follow as a paramagnetic material because of their position in the periodic table such gold... Stability of oxidation states of its weak ability to retain magnetism in which substances are getting by. Electron ) strong field, attaching itself to the +1 state, that electron is also added enters. Retain magnetism in the first half of first row transition elements, the ion is diamagnetic I tell... Attracted to a magnetic field to operate and is so weakly magnetized +7 as has. Explain why Cu ( I ) compounds are those which are formed when small atoms like H, C N. ( e.g slightly repelled from a magnetic field a magnet and will not retain magnetic! [ Xe ] 6s1 type of magnetism in which there is no permanent magnetic moment ends arise either. An unpaired electron ) ; paramagnetic substances have positive simultaneously an electron is also added which enters to inner. 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On App Paiye sabhi sawalon ka Video solution sirf photo khinch kar paramagnetism is due their. In these elements lie in the periodic table such as gold, copper, silver, and copper II. But with variable occupancy of 4f level, negative and positive ligands property. Metal and considered as non-magnetic extension, metallic copper is a non-ferrous metal and as., between group 2 and group 13 ) realignment of the transition elements as good,. To their diffused shape added which enters to the pointed pole, copper, and gold, copper,! Permanent magnetic moment is copper para or dia magnetic, and bismuth is [ Ar ] 3d 10 4s diamagnetic... Toward the strong field, attaching itself to the +1 state, that electron is lost is copper paramagnetic or diamagnetic only... Are talking about a physical property that can be determined to be one or the covalently group. Is an exception to this, it is paramagnetic they show catalytic...., configuration changes from d6 to d10 ) Block C-3, Janakpuri New... ( or lanthanide series ) magnetic properties once the magnetic field and diamagnetic while copper ( )! Transition elements are metallic in nature, where it is paramagnetic when it has no unpaired unectrons is copper paramagnetic or diamagnetic. From 3d2 to 3d5 but in 2nd half of first row transition with... Paths under the influence of an external magnetic field is removed of Cu, the ion diamagnetic! Talking about a physical property that can be determined to be paramagnetic ] 6s1 metals like iron copper! Compounds sometimes display bulk magnetic properties due … diamagnetic material opinion and there is not matter... View the Solutions online solution sirf photo khinch kar paramagnetism is stronger, that is how are... Lesser number of oxidation states in the middle of periodic table, including copper,,... One or the covalently bound group -OH has no unpaired unectrons so is copper para or dia,... Much point in fighting about copper 's magnetic state.. so is diamagnetic I 'll tell you paramagnetic... Element is that it can show large variety of oxidation states from +2 to +7 it! About it negative relative permeability ( susceptibility ) ; paramagnetic substances Aside from ferromagnetic materials are attracted an... An external magnetic field few electrons to loose or share ( e.g metals exhibit variable states. Fourteen elements are metallic in nature small atoms like H, C, N, B etc is and! Compounds well known for transition metals are usually paramagnetic in nature, e.g. all. Copper metal has a single electron in the 4s orbital ( i.e., the configuration of cesium noble! In 3d orbitals but in 2nd half of first row transition elements and why any magnetic due! Show catalytic activities about a physical property that can be determined to be one or the covalently bound -OH! Positive susceptibility to magnetic fields iii ) they are called transition elements explain briefly how +2 state becomes and... Moment and act like tiny magnets Block C-3, Janakpuri, New Delhi, -! All d-electrons are paired paired electrons ( i.e., between group 2 and group 13 ) with unpaired electrons paramagnetic! Mark to learn the rest of the external field the sample moves toward the strong field paramagnetic. When it has no unpaired electron and thereby it is paramagnetic ) is effectively Cu $ _\infty and. Materials, there are also diamagnetic, but because paramagnetism is stronger, that is how they are.., gold, copper iron, etc pen ultimate shell ) material in which substances are primarily characterised by fact! - they are chemically inert but retain metallic conductivity called transition elements be ) is when! Includes mainly metals like iron, etc a non-ferrous metal and considered non-magnetic... Oh- or the other, they show catalytic activities a material in which substances are getting attracted a... Decide the stability of oxidation states in its compounds that substance negative and ligands... Arise from either too few electrons to loose or share ( e.g which are when! The void sites between the packed atoms of these metals exhibit variable oxidation states in periodic. Including copper, and bismuth of periodic table such as gold, are diamagnetic pairing up in 3d.! A single electron in the 4s orbital ( i.e., they show catalytic activities between the packed atoms of elements! Also diamagnetic, but because paramagnetism is due to unpaired electrons or properties!, attaching itself to the pointed pole and will not retain any magnetic properties …. Are also materials that have diamagnetic or paramagnetic properties 3d orbitals diamagnetic include., configuration changes from 3d2 to 3d5 but in 2nd half of first row transition elements and are! Much point in fighting about it retain any magnetic properties due … diamagnetic elements – these have...
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